Abstract

The mechanism of synthesis of acridones based on treatment of diphenylamine-2-carboxylic acid with phosphorus oxychloride is considered. It is established that triphenylamine-2-carboxylic acid and the anilide of diphenylamine-2-carboxylic acid, when treated with phosphorus oxychloride, give high yield of 10-phenylacridone and 9-anilinoacridone respectively. The hitherto undescribed N-(o-chlorobenzoyl)diphenylamine-2-carboxyanilide is obtained by reacting phenylanthranilanilide with o-chlorobenzoyl chloride, or by heating o-chlorobenzanilide with copper powder in nitrobenzene.

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