Abstract

The reaction of cationic carbyne complexes of manganese and rhenium, [η5-C5H5(CO)2M⋮CC6H5]BBr4 (1, M = Mn; 2, M = Re), with [(Ph3P)2N][Rh(CO)4] in THF at low temperature gives the novel Mn2−Rh2 mix...

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