Abstract
The extrathermodynamic assumption of Lejaille and Bessiere that Δ1,2 log K (LMn+)=−ΔGtr (Mn+) in which K is stability constant and L is cryptand 2.2.2, 2B2B2, 2.2.1, or 2.1.1 has been tested in dipolar aprotic solvents for Mn+ being Li+, Na+, K+, Ag+, Tl+, and Ba2+. The relation has been found generally acceptable for the dipolar aprotic solvents propylene carbonate, acetonitrile, N,N-dimethylformamide and dimethylsulfoxide, provided the size of the ion is equal to or smaller than the cavity of the cryptand. The relation does not hold for the hydrogen bonded donating solvents, water, and methanol.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
