Abstract
AbstractWe report an acid‐catalyzed cycloaddition reaction of hydrazones with β‐bromo‐ or β‐chloro‐β‐nitrostyrenes for the regioselective synthesis of 4‐nitro‐ or 4‐chloro‐tetrasubstituted pyrazoles. Arising from a common 4‐halo‐4‐nitropyrazolidine intermediate, the identity of the pyrazole product formed is dependent on the relative leaving group abilities of the halo and nitro substituents.
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