Abstract
The organofluorine chemistry field has steadily increased over the years. In particular, the difunctionalization of unsaturated compounds is an efficient pathway toward the formation of regioselective and highly functionalized aliphatic compounds. This review depicts the recent advances made for simultaneously forming C−FG1 and C−CF2FG2 on alkenes (FG = functional group) by catalysis. This review highlights approaches involving transition metal-catalyzed transformations and one electron manifold.
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