Abstract

The H2 reduction of graphite intercalation compounds (GICs) with nickel and iron chlorides before and after fluorination with BrF3 solutions in HF has been studied by X-ray diffraction, thermal analysis, and Raman scattering spectroscopy. The results indicate that, up to 700°C, the thermolysis of the GICs with nickel and iron chlorides does not reach completion. Thermolysis of the fluorinated GICs in a hydrogen atmosphere at 600°C can be used to fabricate metal-graphite composites. This behavior is interpreted in terms of the thermal properties of the GICs.

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