Abstract

This study investigates the impact of different nitridation processes on hafnium silicon oxynitride (HfSiON) dielectrics. It is demonstrated that the threshold voltage ( V T vs. L g) behavior at short gate lengths is strongly impacted by the nitridation process, depending on the Hf/(Hf+Si) ratio and the HfSiON thickness. A Plasma nitridation in oxidizing ambient results in a modification of the dielectric that can explain the anomalous V T behavior in devices integrated with hafnium-based dielectrics and metal gate. Reduction in anomalous V T behavior and limited gate leakage is achieved by applying a thermal nitridation in a NH 3 ambient on Hf-rich silicon oxynitride.

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