Abstract
The first immobilization of recyclable Taniaphos/copper(Ⅰ) complex on a commercial accessible silica by thiol-ene coupling reaction has been achieved. The immobilization strategy and linker length are found to have significant impact on catalyst selectivities. Furthermore, we have realized the first heterogeneous asymmetric allylic alkylation reactions involving organometallic reagents using this catalyst system, and three types of cinnamyl bromide substrates are found to be suitable with up to 95% enantioselectivity and 96% yield. Notably, the catalyst shows good stability and cyclicity after five recycles without loss of selectivity and the products can be easily isolated with > 95% purity without chromatography purification.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
