Abstract
A recyclable fac-tris(heptadecanyl-2-phenylpyridine) iridium [fac-Ir(hdppy)3] photocatalyst was synthesized. The hexane-phase-selective solubility of fac-Ir(hdppy)3 in a thermomorphic multicomponent solvent (TMS) allowed its easy recycling by automatic liquid/liquid separation at room temperature. The excellent catalytic and recoverable activities of fac-Ir(hdppy)3 were demonstrated via trifuoromethylation and difluoroacetylation reactions of phenyl 3-phenylpropiolate under visible-light irradiation in a TMS system.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
