Abstract
Ceria is the main component in glass polishing powders due to its special physico-chemical properties. Glass polishing powder loses its polishing ability gradually during usage due to the accumulation of other compounds on the polishing powder or due to changes in the particle size distribution. The recovery of cerium from the glass polishing waste results in the efficient utilization of natural resources. This paper reviews processes for the recovery of rare earths from polishing waste. Glass polishing powder waste can be reused via physical, physico-chemical or chemical processes by removing silica and/or alumina. The removal of silica and/or alumina only improves the life span up to some extent. Therefore, removal of other elements by chemical processes is required to recover a cerium or cerium-rich product. However, cerium leaching from the polishing waste is challenging due to the difficulties associated with the dissolution of ceria. Therefore, high acid concentrations, high temperatures or costly reducing agents are required for cerium dissolution. After leaching, cerium can be extracted from the leach solution by solvent extraction or selective precipitation. The product can be used either in glass polishing again or other high value added applications.
Highlights
Rare-Earth ElementsRare-earth elements (REEs) are a group of 17 chemically similar elements that include the lanthanides, yttrium and scandium
Rare-earth elements are divided into light rare-earth elements (LREEs), ranging from lanthanum to europium, and the heavy rare-earth elements (HREEs), ranging from gadolinium to lutetium, and yttrium [1]
Silica can be removed from polishing waste by physical physicochemical processes like sieving, gravity separation, flotation, selective flocculation, etc
Summary
Rare-earth elements (REEs) are a group of 17 chemically similar elements that include the lanthanides, yttrium and scandium. Some of the REEs (Pr, Nd, Eu, Tb, Dy and Y) are important for the low carbon economy, as they are used in wind turbines, electric vehicles, and energy efficient lighting. These elements comes under the list of critical elements due to the supply risk [4]. The total global cerium containing mineral reserves are estimated to be 30 million tons [7] and the current production of ceria (CeO2) is about 54,400 t (32% of RE oxides). Important applications of cerium includes catalysts, glass consumed by glass industry, out of which about 16,000 tons are being used for polishing additives, polishing, ceramics, phosphors, LEDs etc. Glass industry, out of which about 16,000 tons are being used for polishing applications [8]
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