Abstract
Lithium-rich layered powders, Li2MnO3-stabilized LiMO2 (M = Ni, Co, Mn), are attractive cathode candidates for the next generations of high energy lithium-ion batteries. However, most of the state-of-the-art preparation procedures are complicated and require multiple energy-intensive reaction steps. Thus, elucidating a low-cost synthetic protocol is important for the application of these materials in future lithium-ion batteries. Recent developments in the synthesis procedures of lithium rich layered powders are discussed and future directions are pointed out in this review.
Highlights
ENERGY RESEARCHRecent developments in synthesis of xLi2MnO3 · (1 − x )LiMO2 (M = Ni, Co, Mn) cathode powders for high-energy lithium rechargeable batteries
From its first commercial introduction by Sony in 1991, the LiCoO2 cathode has been widely used in portable electronics due to its excellent rate capability, cyclability, and high-tap density (Ying et al, 2004; He et al, 2006)
As-prepared powders are rinsed with water, and vacuum dried at 120°C
Summary
Recent developments in synthesis of xLi2MnO3 · (1 − x )LiMO2 (M = Ni, Co, Mn) cathode powders for high-energy lithium rechargeable batteries. Reviewed by: Reza Younesi, Technical University of Denmark, Denmark Zhaoxiang Wang, Chinese Academy of Sciences, China Hao Liu, Chinese Academy of Engineering Physics, China. Lithium-rich layered powders, Li2MnO3-stabilized LiMO2 (M = Ni, Co, Mn), are attractive cathode candidates for the generations of high-energy lithium-ion batteries. Most of the state-of-the-art preparation procedures are complicated and require multiple energy-intensive reaction steps. Elucidating a low-cost synthetic protocol is important for the application of these materials in future lithium-ion batteries. Recent developments in the synthesis procedures of lithium-rich layered powders are discussed and future directions are pointed out in this review
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