Recent advances in carbonaceous catalyst design for the in situ production of [formula omitted] via two-electron oxygen reduction

Abstract

The electrochemical oxygen reduction reaction has received increasing attention as a relatively green, safe and sustainable method for in situ hydrogen peroxide (H2O2) production. Recently, significant achievements have been made to explore carbon-based (noble metal-free) low-cost and efficient electrocatalysts for H2O2 electroproduction, which could potentially replace the traditional anthraquinone process. However, to realize industrial-scale implementation, a highly active and selective catalytic material is needed. In this review paper, we first expound on the oxygen reduction reaction (ORR) mechanism, which is the origin of in situ H2O2 production. Then, the recent progress in the development of modified carbon-based catalysts is reviewed and classified, corresponding to their physical or chemical modulation. Furthermore, an overview is provided of the available examples from pilot/large-scale applications. Finally, an outlook on the current challenges and future research prospects to transfer the lab-developed catalysts into pilot or industrial-scale reactors is briefly discussed.