Abstract
Rearrangements of four possible stereoisomers of 6-tert-butyl-2-(1'-mesyloxy)ethyl-2-methyltetrahydropyran with Zn(OAc) 2 in aq. AcOH were investigated. Rearrangement-ring expansion and/or rearrangement-ring opening reactions took place depending on the stereostructure of the substrates.
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