Abstract
The reactivity of technical P 4 S 10 with alcohols or water, in either heterogeneous or homogeneous processes, is a direct function of its solidification rate, which determines to what extent the dissociated state prevailing in the molten sulfide is retained in the solid. 31 P NMR analysis reveals that quenched melts of P 4 S 10 contain more redox products P 4 S 9 , P 4 S 7 , and phosphorus polysulfides P m S y (y/m>2.5) but seemingly less elemental sulfur than slowly cooled (unquenched) or annealed specimens
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