Abstract
The pulse radiolysis technique has been used to determine rate constants for the initiation step in cationic polymerization. The reactivity of the benzyl cation and of the benzhydryl cation toward some 13 alkenes in dichloroethane solution has been determined. The rate constants vary over four orders of magnitude with the molecular structure of the nucleophiles. The reactivity-molecular structue dependence is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
