Abstract

1. A study was made of the diene condensation of the cis and trans isomers of 2-bromovinyl ethyl ether with hexachlorocyclopentadiene and with cyclopentadiene. Under the conditions studied only cis-2-bromovinyl ethyl ether forms an adduct with hexachlorocyclopentadiene. 2. The cis and trans isomers of 2-bromovinyl ethyl ether were brought into reaction with acetaldehyde diethyl acetal. 2-Bromo-1,1,3-triethoxybutane was isolated and characterized, and its structure was proved. 3. 2-Bromovinyl ethyl, 2-bromovinyl isopropyl, and 2-bromovinyl butyl ether were brought into reaction with phosphorus pentachloride, and the resulting 2-alkoxy-1-bromovinylphosphonic dichlorides were isolated and characterized.

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