Abstract

tert-Butyl, cyclohexyl, n-propyl, and n-dodecyl vinyl ethers have been used as comonomers with styrene and methyl methacrylate using 13 C-enriched samples of azobis(isobutyronitrile) and benzoyl peroxide as initiators at 60°C. Examination by 13 C-NMR spectroscopy of either ( 13 CH 3 ) 2 C(CN)- or Ph 13 COO- end-groups in the products has shown that the vinyl ethers have low reactivities toward the 2-cyano-2-propyl radical but high reactivities toward the benzoyloxy radical.

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