Abstract
New methods have been developed for the synthesis of previously unknown ω-(hexacyclo[9.2.1.02,7.03,5.04,8.09,13]tetradecan-10-exo-yloxy)alkan-1-ols and hexacyclo[9.2.1.02,7.03,5.04,8.09,13]tetradecan-10-exo-yl carboxylates by reactions of heptacyclo[8.4.0.02,12.03,8.04,6.05,9.011,13]tetradecane (binor-S) with α,ω-diols and organic acids in the presence of inorganic ionic liquids at 120–150°C for 6–8 h. The reactions involved regioselective cleavage of the cyclopropane C4–C5 bond of binor-S.
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