Abstract
Degenerate substitution reactions (at carbon) between the appropriate sulfinic acid salts and tosylmethyl methyl or mesylmethyl methyl disulfides have formed symmetrical disulfone disulfides in moderate yields. These products form in a redox process involving sulfinate anions following partial skeletal disassembly arising from rupture of the SS bond. The reaction of mesylmethyl methyl disulfide and sodium methanesulfinate provides a natural product, dysoxysulfone, in low yield.
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