Abstract
Ionically conducting hydrophilic polymer electrolytes have generated interest in the context of a variety of fundamental problems and electrochemical applications, such as power sources and sensors. Fundamental aspects of hydrophilic polymer electrolytes include conductance mechanism research, analysis of adsorptive options at the polymer electrolyte/electrode interface, catalysis of dioxygen reduction and dihydrogen oxidation at this interface and current generation mechanism in electrochemical reactions. We consider and analyse these problems for some systems on the base of poly(vinyl alcohol), polyacrylic acid, their polymers, etc.
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