Abstract
AbstractThe phosphenium ion [(i‐Pr2N)CIP]+ (1) reacts with crotonaldehyde dimethylhydrazone (2) to afford a product with a C3NP ring system (4). The reaction of 1 with acetone azine (3) results in a novel tricyclic compound (6) which features a C2N2P2 and two C2N2P rings. The structures of 4 and 6 were established by X‐ray crystallography. Compound 4, C12H26AlCl3N3OP, crystallizes in the monoclinic space group P21/n with Z = 4, a = 15.400(6), b = 14.442(4), c = 9.206(3) Å, and β = 93.33(3)°. Compound 6, C12H22Al2Cl6N4O2P2, crystallizes in the triclinic group P1 with Z = 1, a = 8.556(1), b = 9.782(1), c = 8.119(1) Å, α = 94.48(1), β = 104.97(1), and γ = 78.35(1)°.
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