Abstract
1-Cyclohexyl-2-cyclohexylaminomethylene-4,5-diphenyl-1,2-dihydropyrrol-3-one 4a and 1-aryl-2-arylaminomethylene-4,5-diphenyl-1,2-dihydropyrrol-3-ones 4b,c as the E-form are synthesized by the reaction between N,N′-dicyclohexylethane-1,2-diylidenediamine 2a and N,N′-diarylethane-1,2-diylidenediamines 2b,c with diphenylcyclopropenone 1 through a formal [2 + 3] cycloaddition reaction. The structure assignment of 4a is confirmed on the basis of an X-ray crystal-structure determination. Similarly, diaryl azines 8a–c react with 1 through a formal [2 + 3] cycloaddition reaction to give the non-isolable product Δ4-pyrrolin-3-ones 10a–c which undergo oxidative rearrangement to afford ultimately the indenone derivatives 9a–c.
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