Abstract
The maximum yields of oxygen atoms, estimated at different levels in a long-tube reactor by gas-phase "titration" with NO2, were equal for the reactions of active nitrogen with NO and O2. In this reactor, the maximum oxygen-atom production from the oxygen reaction, determined by the amount of N2O3 produced with excess NO2, was found to correspond to the NO "titration" value for the active nitrogen and not to the maximum amount of HCN produced in the active nitrogen – ethylene reaction. A second-order rate constant, [Formula: see text] [Formula: see text]was obtained for the active nitrogen – oxygen reaction.Experiments in a short reactor showed that the validity of the analytical method based on the trapping of N2O3 depended upon adequate reaction time for the NO + NO2 reaction to occur.
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