Abstract
A statistical moment method based on the overall elution profile is developed for a (pseudo-) first-order chemical reaction occurring in a chromatographic reactor. Application of this method is illustrated for a hydroquinone oxidation catalyzed by an iron-modified chromatographic silica in an organic environment. The effects of some mass-transfer processes on intrinsic kinetics for reactions occurring in a liquid chromatographic column are also examined. A simple reaction model and a model incorporating finite adsorption and desorption rates together with reaction are both developed
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