Abstract
From recent rate constant data for the recombination reaction 2CF 3 • → C2F6 ( % MathType!MTEF!2!1!+- % feaagaart1ev2aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqr1ngB % PrgifHhDYfgasaacH8WrFz0dbbf9q8WrFfeuY-Hhbbf9v8qqaqFr0d % d9qqFj0dXdbba91qpepGe9FjuP0-is0dXdbba9pGe9xq-Jbba9suk9 % fr-xfr-xfrpeWZqaaeaabiGaciaacaqabeaadaqaaqaaaOqaaiaadU % gadaqhaaWcbaGaaiikaGqaaiaa-neacaWFgbWaaSbaaWqaaiaaioda % aeqaaSGaaiykamaaBaaameaacaaIYaaabeaaaSqaaiaa-1eaaaaaaa!41E8! $$ k_{(CF_3 )_2 }^M $$ ) in the high-pressure limit and from experimental data obtained at intermediate pressures of buffer gases M (M = He, Ar, N2, CF3I), analytical expressions for % MathType!MTEF!2!1!+- % feaagaart1ev2aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqr1ngB % PrgifHhDYfgasaacH8WrFz0dbbf9q8WrFfeuY-Hhbbf9v8qqaqFr0d % d9qqFj0dXdbba91qpepGe9FjuP0-is0dXdbba9pGe9xq-Jbba9suk9 % fr-xfr-xfrpeWZqaaeaabiGaciaacaqabeaadaqaaqaaaOqaaiaadU % gadaqhaaWcbaGaaiikaGqaaiaa-neacaWFgbWaaSbaaWqaaiaaioda % aeqaaSGaaiykamaaBaaameaacaaIYaaabeaaaSqaaiaa-1eaaaaaaa!41E8! $$ k_{(CF_3 )_2 }^M $$ (in Lindemann’s formulation) are derived for the temperature range of 300–1300 K and intermediate pressures of the buffer gases.
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