Abstract

I: Properties of Catalytic Surfaces 1.- 1.1 EPR Characterization of Oxide Supported Transition Metal Ions: Relevance to Catalysis.- 1.2 Study of Catalytic Site Structure and Diffusion of Radicals in Porous Heterogeneous Systems with ESR, ENDOR and ESE.- 1.3 Theoretical Studies of Core Ionization, Excitation and De-excitation of Adsorbates.- II: Structure and Reactivity of Radicals on Surfaces 87.- II. 1 Electron Magnetic Resonance of Aromatic Radicals on Metal Oxide Surfaces 89.- II.2 ESR Studies of Organic Radical Cations in Zeolites.- II.3 Surface Trapped Electrons on Metal Vapour Modified Magnesium Oxide. Nature of Surface Centres and Reactivity with Adsorbed Molecules.- II.4 Radicals on Surfaces Formed by Ionizing Radiation.- II.5 Photostimulated Formation of Radicals on Oxide Surfaces.- III: Trends in Modern Techniques 227.- III. 1 Fourier Transform Electron Paramagnetic Resonance Studies of Photochemical Reactions in Heterogeneous Media.- III.2 Muon Spin Resonance of Radicals on Surfaces.- III.3 Investigation of Radical Ions with Time-Resolved Surface Enhanced Raman Spectroscopy.

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