Abstract

AbstractAcrylic acid copolymers bearing radically polymerizable methacrylic and itaconic moieties are synthesized. Starting from copolymers of tBA and APVE, prepared at different ratios, methacrylic or itaconic amides are obtained via polymer‐analogous reaction. After acidic elimination of isobutylene, polymers with free carbon acids and staggered reactivity can be prepared. Varying amounts of attached acrylamide moieties allow the adjustment of network densities. Rheological properties in HEMA/water matrices during curing are evaluated.

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