Abstract
The reaction of 2-methylisoselenochromanium salt with Grignard reagents afforded the reductive ring-opened product by the single electron transfer (SET) mechanism, not by the self-decomposition of σ-selenurane. The same reduction was observed in the reaction of the selenonium salt with magnesium metal. Some other selenonium salts were easily reduced by magnesium metal to give ring-opened products.
Published Version
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