Abstract
AbstractP‐Phenyl C‐aminophosphaalkenes 1 react with some disubstituted diazocompounds at −20°C leading to tricoordinated phosphorus compounds 2, 9, 11 and 12 via a Staudinger type reaction. These compounds decompose already at room temperature and quickly by heating. Azines are isolated after extrusion of phenyl phosphinidene.
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