Abstract
The title compound, [Rh(C15H16PS)(C18H15P)(CO)], was synthesized from the reaction of the ligand rac-[Ph2PCH2CH(CH3)SH] with trans-[Rh(F)(CO)(PPh3)2] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph2PCH2CH(CH3)S] acting as a chelate and the PPh3 and disordered CO [site occupation factors of 0.61 (5) and 0.39 (5)] ligands completing the coordination.
Highlights
The Rh atom is four-coordinated in a distorted square-planar geometry with the P—S ligand [Ph2PCH2CH(CH3)S] acting as a chelate and the PPh3 and disordered CO [site occupation factors of 0.61 (5) and 0.39 (5)] ligands completing the coordination
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: DN2386)
120.4 (5) 119.8 119.8 120.6 (5) 119.7 119.7 108.1 (3) 110.1 110.1 110.1 110.1 108.4 supporting information C31—C30—C29 C31—C30—H30 C29—C30—H30 C30—C31—C32 C30—C31—H31 C32—C31—H31 C31—C32—C33 C31—C32—H32 C33—C32—H32 C28—C33—C32 C28—C33—H33 C32—C33—H33
Summary
ISSN 1600-5368 rac-Carbonyl{1-[(diphenylphosphino)methyl]ethanethiolato}(triphenylphosphine)rhodium(I) Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.008 A; disorder in main residue; R factor = 0.049; wR factor = 0.108; data-to-parameter ratio = 15.0. Crystal data [Rh(C15H16PS)(C18H15P)(CO)] Mr = 652.50 Orthorhombic, Pbca a = 10.3142 (7) Ab = 16.865 (1) Ac = 34.984 (2) A
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