Abstract

A new hetero-bimetallic trinuclear macrocycle has been self-assembled quantitatively, in one step, by means of axial Zn II–N and 90° angular Pt II–N binding, with the metallated angular bisporphyrin, the cis-square-planar platinum bistriflate complex and the linear 4,4 ′-bipyridine, as building block units.

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