Abstract

The variation of ionic mobilities with size, solvent properties, temperature, and pressure remains one of the unsolved problems of transport theory. The Zwanzig equation, which is based on the continuum model for the solvent, is the ultimate that has been devised at this time. Although the Zwanzig equation successfully predicts many of the qualitative features of this transport property, the extent to which the theory is applicable in a quantitative manner has not been critically reviewed in the literature. This aspect of the Zwanzig equation will be discussed using ionic molibities in water, acetonitrile, nitromethane and the alcohols, methanol through butanol.

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