Abstract
The photovoltaic industry generates large amounts of waste graphite (WG) that contains useful metals that can be recycled into high-value products. This study elucidated the impurity elements and their existence states in WG, analyzed and verified the source of the main impurity phase SiC, and determined the SiC content to be 4.66%. WG was purified using an alkaline-acid method, whose optimal process parameters were a solid alkali ratio of 3, calcination temperature of 600 °C, calcination time of 120 min, HCl concentration of 1 M, and acid leaching time of 40 min. Under these conditions, a graphite product with a fixed carbon content of 98.45% was obtained. Impurities were determined to migrate via three pathways: (1) Most main elements (Al, K, and Si) in silicates were removed by alkaline roasting, while the remaining elements were dissolved in acid. (2) Impurities containing metal elements such as Fe, Mg, Ca, and Zn were decomposed in NaOH to form hydroxides or oxides that were dissolved in HCl. (3) Silicon carbide impurities were removed by the alkaline-acid method without decomposition and often existed with graphite in the acid-leaching slag.
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