Abstract

The phosphonium ylide triphenylphosphonium methylide Ph3PCH2 reacts with 2,4,6-trimethyiphenol to give the phosphonium aryloxide dimer [(Ph3PMe)+(OC6H2Me3-2,4,6)–]21, in the solid state, in which aggregation is solely through C–H ⋯ O hydrogen bonding from both alkyl and aryl donors within the phosphonium cation, resulting in each phenoxide oxygen acceptor being five-coordinate (tetrafurcated).

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