Abstract
Novel proton di-ionizable p-tert-butylcalix[4]arene-crown-6 compounds in cone, partial-cone and 1,3-alternate conformations are synthesized to compare the efficiency and selectivity with which they extract alkaline earth metal ions. In these ligands, a crown-6 polyether unit links alternate aromatic rings of the calix[4]arene framework. To the remaining lower-rim positions are attached oxyacetic acid or N-(X)sulfonyl oxyacetamide groups. Changing the conformation varies the spatial relationship between a polyether-complexed divalent metal ion and the ionized side arms of the ligands. This is found to markedly affect the efficiency and selectivity in competitive solvent extraction of alkaline earth metal ions from aqueous solutions into chloroform by the di-ionizable calix[4]arene-crown-6 ligands.
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