Production of Hydrogen Peroxide and Organic Hydroperoxides in the Reactions of Ozone with Natural Hydrocarbons in Air

Shiro Hatakeyama,Shidong Gao,Haiping Lai,Kentaro Murano

doi:10.1246/cl.1993.1287

Production of Hydrogen Peroxide and Organic Hydroperoxides in the Reactions of Ozone with Natural Hydrocarbons in Air

Shiro Hatakeyama, Shidong Gao + Show 2 more

https://doi.org/10.1246/cl.1993.1287

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Journal: Chemistry Letters	Publication Date: Aug 1, 1993
Citations: 37

Affiliation: National Institute for Environmental Studies

#Kinds Of Olefins #Detailed Reaction Mechanisms + Show 8 more

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Abstract

Abstract Reaction of ozone with three kinds of olefins in air was studied. H2O2, CH3OOH, and HOCH2OOH were collected and analyzed with HPLC with a fluorometric detector. Direct reaction of CH2OO with H2O was found to be the source of HOCH2OOH. CH3OOH was formed only from the olefins which have a methyl group. Detailed reaction mechanisms are discussed.

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