Abstract
The NMR relaxation behavior of a polar molecular liquid, acetonitrile- d 3, confined to porous silica glasses prepared by a sol- gel process, was studied at pressures up to 5 kbar at 300 K. Analysis of the relaxation data in terms of the two-state fast exchange model and the classical rotational diffusion equation allowed us to determine the pressure effects on the anisotropic rotational diffusion of acetonitrile- d 3 in confined geometry.
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