Abstract
The preparation and characterization of five new hydroxyalkyl silicon compounds, (hydroxymethyl)pentamethyldisilane, (α-hydroxyethyl)- and (β-hydroxyethyl)pentamethyldisilane and α-hydroxyethyl)- and (β-hydroxyethyl)-tert-butyldimethylsilane are described. In hydroboration of vinylsilanes used here, all the organosilicon substituents attached to the vinyl group, i.e., (CH 3) 3Si, (CH 3) 3SiSi(CH 3) 2 and (CH 3) 3CSi(CH 3) 2, showed a marked tendency, as compared with any alkyl substituent, to direct a boron atom to become bonded to the α-carbon of the vinyl.
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