Abstract
In this study, a novel modified chitosan composite adsorbent (UNCS) was prepared by crosslinking between chitosan and metal organic frameworks (MOFs) material UiO-66-NH2 using epichlorohydrin as crosslinker. The influence of the prepared conditions was investigated. The structure and morphology of the composite were characterized by FT-IR, XRD, SEM, TGA, BET and zeta potential analysis. Effects of different variables for adsorption of Hg(II) on this adsorbent were explored. The kinetic studies indicated that the adsorption process followed the pseudo-second-order kinetic model and the adsorption equilibrium could be reached within 2 h. The adsorption was mainly controlled by chemical process. Adsorption isothermal studies illustrated that the adsorption fitted Langmuir isotherm model, implying the homogeneous adsorption on the surface of the adsorbent. The adsorbent exhibited high uptake and the maximum capacity from Langmuir model could reach 896.8 mg g−1 at pH 6. Thermodynamic studies showed the spontaneous nature and exothermic nature of the adsorption process. Additionally, the removal of Hg(II) on UNCS could achieve over 90 %. The adsorption-desorption cycled experiments indicated the appropriate reusability of the adsorbent. Hence, this adsorbent would be promising for the removal of Hg(II) from wastewater.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: International Journal of Biological Macromolecules
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
