Abstract
Cobaloxime complex [(H 2 O)(dimethylglyoxime) 2 Co(I)] (generated in situ) reacts with an allenic electrophile to produce 1,3-butadien-2-yl(H 2 O)bis(dimethylglyoximato)cobalt(III). This dienyl complex (which has also been characterized by X-ray crystallography) reacts with a number of dienophiles in both water and organic solvents.
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