Abstract

Polyurethane (PU) foams and sheets were prepared from molasses (MOL) solutions in polyethylene glycol having molecular weights of 200 and 400 (PEG 200 and 400) and diphenylmethane diisocyanate (MDI). For the preparation of foams, small amounts of di-n-butyltin dilaurate (catalyst), silicone oil (surfactant) and water (foaming reagent) were added to the above reaction system. The thermal decomposition temperatures, which were determined by thermogravimetry (TG), decreased slightly with increasing MOL content of PU's. The glass transition temperatures, which were obtained by differential scanning calorimetry (DSC), increased with the increase in MOL content of PU's suggesting that MOL exists at crosslinking points and reduces main chain motion of PU's. The increase in modulus and strength of foams and sheets was observed in compression and tensile tests when MOL contents in PU foams and sheets were increased.

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