Abstract
The radical salts of NiPc, PtPc, and NiTBP were prepared by the method of electrochemical oxidation. The radical salts of NiPc and PtPc have 2:1 chemical composition and are metallic, the crystal structure being composed of tetragonally packed molecular columns with the metal-over-metal stacking mode. On the other hand, the radical salts of NiTBP with tetrahedral and octahedral counter anions have 3:2 chemical composition and are semiconductive, the crystal structure being composed of hexagonally packed molecular columns including a periodic unit of NiTBP trimer. All these materials have predominantly oxidized macrocycles, a small on-site Coulomb energy, and a small electron-phonon interaction.
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