Abstract
The retention of a series of non-polar solutes in reversed-phase liquid chromatography was studied as a function of column temperature and mobile phase composition using methanol—water mixtures. The enthalpy change on transferring a solute from a stationary phase to a mobile phase was predicted from physicochemical parameters of the solute on elution with methanol—water between 40:60 and 100:0 by using the solubility concept model.
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