Abstract

In this work, we attempt to predict specific retention volumes in gas-liquid chromatographic systems by using the interaction energy parameters D and ϕ, suggested in a previous paper. The investigations hve been carried out for 27 polar solutes on the OV-101, OV-17 and oxidipropionitrile stationary phases. The applicability of the parameters D and ϕ for solving practical prediction problems is demonstrated.

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