Precipitation strengthening and thermal stability in a conventionally non-heat treatable AA3xxx aluminium alloy

Abstract

We report an unexpected yet significant precipitation-strengthening effect with remarkable thermal stability in an otherwise conventionally non-heat treatable AA3104 aluminium alloy. We reveal that a minor addition of Cu plays a critical role in the alloy's strength and thermal stability, and explain the underpinning mechanisms. The primary strengthening β′ phase can be engineered to exhibit distinctive structural characteristics, including regularly-spaced Cu atom columns at the coherent β′/Al interfaces, stacking faults and resultant domains. Our atomistic simulations rationalise that these microscopic characteristics are directly promoted by the Cu addition. The Cu-decorated interfaces promote β′ phase nucleation and result in strong, directional covalent-like Cu-Si bonding at the β′/Al interfaces. Specifically, the interfacial Cu columns increase the work of separation of the habit-plane interfaces and reduce the interface energy, resulting in significant strengthening and stabilising effects. The Cu columns also facilitate the stacking fault formation in the β′ phase. Collectively, these features enhance the strengthening effect and thermal stability of the precipitates. This study demonstrates the potential for exploring "new" features in "old" alloys to advance alloy science and technology.