Precipitation of Copper in Germanium

Abstract

The density of dislocations is shown to have a marked effect on the rate of anneal of copper in germanium. At 500\ifmmode^\circ\else\textdegree\fi{}C samples containing high dislocation density (\ensuremath{\sim}${10}^{6}$/${\mathrm{cm}}^{2}$) anneal in about 1 hour in contrast to material of low dislocation density (\ensuremath{\sim}${10}^{4}$/${\mathrm{cm}}^{2}$) which requires about 24 hours. When copper-doped germanium is cooled from a high temperature in regions of high dislocation density, significant precipitation occurs in a cooling cycle of only a few seconds. In this case, in order to prevent precipitation the sample must be quenched from the high temperature in a time of the order of 0.1 second.