Abstract

Powdered sludge carbons were prepared by pyrolysis at 800 °C and used for the first time as microparticle electrodes of a three-dimensional electrode reactor. It was found that acid orange 7 (AO7) could be efficiently removed by adsorption and electro-oxidation. The electrochemical oxidation could degrade both AO7 in aqueous solution and AO7 adsorbed on the microparticle electrodes. The degradation efficiency of the former reached 80.2%, and that of the latter is estimated to be 13.6% of the adsorption amount under the conditions of 20 V cell voltage, 300 mL min–1 airflow, and 60 min reaction time. This degradation is a result of not only the electrocatalytic activity of the carbon component but also the electro-Fenton-like effect of Fe3O4 and the co-Fenton-like effect of SiO2 and Al2O3 in the sludge carbon.

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