Abstract

It has been shown that polyvinyl alcohol — ferric chloride support can act as a catalyst — oxidant for chemical polymerization of pyrrole on its surface. The laminate so formed is highly conducting (15 S/cm) and exhibits good mechanical properties. Mössbauer and EPR studies are consistent with the proposal of oxidative polymerization which involves the insertion of Cl − as the ionic species neutralizing the polycarbonium cation.

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