Abstract

Both preferential sorption and second virial coefficients for PMMA-CCl 4-chloroalkane (butyl chloride, sec. butyl chloride and tert. butyl chloride) have been studied by laser light scattering and differential refractometry of equilibrium dialysis at 298 K. The results indicate that the chloroalkane is always preferentially adsorbed on PMMA. In order to predict the experimental values of the preferential sorption coefficient, Read's equation has been used.

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