Abstract

The title compound, {[Cu2(C10H8N2)3](ClO4)2·2H2O}n, forms a three-dimensional network containing one-dimensional nanoporous channels, accommodating guest water mol­ecules and perchlorate anions. The network consists of [Cu2(4,4′-bipyridyl)3]2+ cations containing trigonal planar CuI centers bonded to three 4,4′-bipyridyl groups.

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